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Formic Acid Liquid CAS 64-18-6
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Formic Acid Liquid CAS 64-18-6

Formic Acid Liquid CAS 64-18-6

Product Code: BM-3-2-008
English Name: formal acid
CAS No.: 64-18-6
Molecular formula: ch2o2
Molecular weight: 46.03
EINECS No.: 200-579-1
Quality items: HPLC>99.5%, LC-MS
HS code: 29151100
Main market: USA, Australia, Brazil, Japan, Germany, Indonesia, UK, New Zealand , Canada etc.
Manufacturer: BLOOM TECH Yinchuan Factory
Technology service: R&D Dept.-1

 

Formic Acid Liquid is an organic compound, the chemical formula is HCOOH, molecular weight 46.03, commonly known as ant acid, is the simplest carboxylic acid. A colorless, irritating liquid. Flammable. It can be mixed with water, ethanol, ether and glycerol, and most polar organic solvents, and has a certain solubility in hydrocarbons. Weak electrolyte, strong acidity, corrosive, can stimulate skin blisters. It exists in the secretions of bees, some ants and caterpillars. It is an organic chemical raw material, also used as disinfectant and preservative.

product introduction

Here are some basic chemical information. For specific formal acid price, please send inquiry to email:

Chemical Formula CH2O2
Exact Mass 325
Molecular Weight 325
m/z 46, m/z: 46 (100.0%), 47 (1.1%)
Elemental Analysis C, 26.10; H, 4.38; O, 69.52
Morphological liquid
Color clear, colorless
Melting point 8.2-8.4 ° C (lit.)
Boiling point 100-101 ° C (lit.)
Density 1.22 g / ml at 25 ° C (lit.)
Storage conditions 2-8 ° C
solubility alcohol 40 parts of solvent
Acidity coefficient ( pKa ) 133 ° f
Flash point 133 ° f
Solubility H2O soluble1g / 10ml
Vapor density 1.03 (vs air)
Refractive index 1.4200 ( estimate )

Formic Acid structure CAS 64-18-6 | Shaanxi BLOOM Tech Co., Ltd

Formic Acid Liquid  | Shaanxi BLOOM Tech Co., Ltd

usage

Formic Acid Liquid is one of the basic organic chemical raw materials, which is widely used in pesticide, leather, dye, medicine, rubber and other industries. Formic acid can be directly used in fabric processing, tanning, textile printing and dyeing and storage of green fodder. It can also be used as metal surface treatment agent, rubber auxiliary and industrial solvent. It is used in organic synthesis to synthesize various formates, acridine dyes and formamide series pharmaceutical intermediates. The specific classification is as follows:

Leather tanning and processing industry

Leather is a century old classic application field of formic acid. Compared with inorganic strong acids such as sulfuric acid and hydrochloric acid, formic acid has mild acidity, uniform penetration, no chloride ion corrosion, and soft and non brittle leather after tanning. It runs through the entire process of ash removal, acid immersion, tanning, neutralization and color fixation, and is an irreplaceable additive for high-quality genuine leather and ecologically chromium free leather.

Core Neutralizer for Leather Ash Removal Process

 

After soaking the raw skin in lime for hair removal and expansion, a large amount of calcium hydroxide lime paste is filled in the gaps between the skin fibers, which must be de ashed to open the collagen fiber structure. Dilute 90% liquid formic acid to a 5% -8% de ashing solution, slowly penetrate the interior of the skin, undergo acid-base neutralization reaction, and generate soluble calcium formate that is washed away with water. Inorganic strong acids can easily cause skin burns, excessive hydrolysis of collagen, and thinning and loosening of the skin plate; 

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Formic Acid Cost | Shaanxi BLOOM Tech Co., Ltd

Formic acid ash removal pH is stably controlled at 6.0-6.5, with uniform skin thickness and intact grain surface. It is standard for mainstream processes such as yellow cattle shoe upper leather, sheep clothing leather, and goat drop grain leather. The consumption of formic acid per ton of wet blue leather is about 12-18kg, and 100% of high-end leather factories in Europe and America adopt formic acid ash removal system.

Acid leaching pretreatment additives

 

After ash removal, the bare skin enters the soaking tank, and formic acid is combined with salt to adjust the pH of the system to 2.8-3.2. Salt inhibits the water absorption and expansion of skin fibers, while formic acid opens collagen peptide bonds, creating conditions for uniform adsorption of chrome tanning agents and vegetable tanning agents. Adequate immersion in acid can significantly reduce chromium salt consumption by 15% -20%, reduce residual pollution of hexavalent chromium, and adapt to the EU REACH ecological leather standard;

Formic Acid For Sale | Shaanxi BLOOM Tech Co., Ltd

Tanning stage pH regulator and tanning aid

 

Formic Acid Price| Shaanxi BLOOM Tech Co., Ltd

The pH of the chrome tanning process system directly determines the binding strength between trivalent chromium and collagen: low pH in the early stage promotes chromium penetration, and slow pH increase in the later stage achieves cross-linking fixation. Liquid formic acid precisely adjusts acidity to avoid local over acidification leading to skin pigmentation; In the processes of white wet leather, chromium free aluminum tanning, and zirconium tanning, formic acid is used as a tanning aid, and metal ions form stable coordination complexes with formate ions. The tanning agent is more evenly dispersed, and the leather's resistance to washing and sweat stains is doubled.

Neutralization, dyeing, and finishing after fixation

 

After tanning, residual acidic tanning agents remain inside the skin. Dilute the sodium formate buffer system to neutralize the acidity inside the skin, balance the overall pH to 4.5-5.0, and prevent mold growth during storage; Leather dyes are mostly acidic dyes, and the dyeing bath relies on formic acid to maintain a stable acidic environment. The dye is firmly bound to the collagen amino group, and the color fastness is improved by 2-3 levels. It is resistant to friction and washing without fading; 

Formic Acid Product | Shaanxi BLOOM Tech Co., Ltd

Recycling and Regeneration Additives for Waste Leather

 

Formic Acid Drug | Shaanxi BLOOM Tech Co., Ltd

When recycling crushed leather, leather scraps, and hydrolyzing to prepare regenerated collagen fibers and artificial leather base fabrics, formic acid gently hydrolyzes collagen macromolecules, with controllable degradation of molecular weight. The toughness of regenerated collagen is close to that of raw leather, replacing the high pollution strong acid hydrolysis process. The waste liquid calcium formate can be recycled and processed into early strength agents for building materials, achieving a circular economy.

Textile printing and dyeing and fiber finishing industry

Cotton, linen, silk, wool, nylon, and polyester are fully equipped with textile pre-treatment, dyeing, shaping, and desizing processes. With the advantages of low addition, stable pH buffering, and no damage to fibers, they replace some acetic acid and inorganic acids and are key acidic auxiliaries for high-end fabric dyeing and finishing.

Fabric pretreatment: desizing, boiling, degreasing, acid washing
 

The raw fabric weaving slurry is mostly starch and PVA alkaline slurry, and the residual alkali must be neutralized and removed after alkaline boiling. Neutralizing and boiling residual alkali with liquid formic acid quickly lowers the pH of the fabric to a neutral acidic state, removing impurities such as cottonseed hulls, wax, and pectin; Wool and silk protein fibers should not be degreased with strong acid or formic acid, which can dissolve the surface oil, scales, and impurities of wool without damaging the protein peptide chain. The fabric should be fluffy and soft, and the silk fabric should have a shiny and transparent luster without yellowing or brittleness. 

Formic Acid Drugs | Shaanxi BLOOM Tech Co., Ltd

Acid dyes, mordant dyes, dyeing promoters

 

Formic Acid Dyes | Shaanxi BLOOM Tech Co., Ltd

Wool, silk, nylon exclusive acid dyes, and chromium based dyes rely entirely on acidic environments for coloring: formic acid slowly releases hydrogen ions, promoting the binding and adsorption of dye anions with fiber amino cations. Compared to acetic acid, formic acid has stronger acidity, with a dosage of only 1/3 of acetic acid at the same pH, resulting in a 40% increase in coloring rate and energy-saving and consumption reducing effects in low-temperature dyeing; When dyeing with chromium media, formic acid also has a reducing effect, reducing harmful hexavalent chromium to stable trivalent chromium, greatly reducing the toxicity of heavy metals in wastewater and meeting the discharge standards for printing and dyeing wastewater. 

Fabric color fixing, wrinkle resistance, and flame retardant finishing
 

After dyeing with reactive dyes, formic acid weakly fixes and blocks unreacted reactive groups, improving wet friction fastness; In the non ironing and wrinkle resistant resin finishing of cotton fabrics, formic acid acts as a resin crosslinking catalyst to accelerate the condensation crosslinking of hydroxymethyl resin and cellulose hydroxyl groups, and low-temperature curing reduces yellowing of high-temperature fabrics; Wool anti insect finishing and silk antibacterial finishing solution pH regulator ensure stable and long-lasting activity of antibacterial and anti insect additives.

Formic Acid Finishing | Shaanxi BLOOM Tech Co., Ltd

Processing of artificial fibers and non-woven fabrics

 

Formic Acid Woven | Shaanxi BLOOM Tech Co., Ltd

Fine tuning of acidity in the coagulation bath for viscose filament and short filament spinning, stabilizing the tension during filament formation with formic acid, and reducing yarn breakage and fuzz; When using water jet non-woven fabric and needle punched filter cloth for immersion disinfection, low concentration formic acid has both acid regulating and antibacterial effects, making medical protective non-woven fabric antibacterial and anticorrosive.

 

Farming feed and breeding disinfection and sterilization

Feed grade liquid formic acid has undergone strict purification of heavy metals, arsenic, and mycotoxins, and has obtained a feed additive license. It is a core non acid resistant preservative under the global ban on antibiotics, covering four major scenarios: silage feed, livestock and poultry feed, aquaculture, and bee industry deworming.

Long term preservatives for green silage feed (maximum agricultural and animal husbandry subdivision)
 

When silage corn stover, alfalfa, ryegrass, and beet residue, fresh forage comes with miscellaneous bacteria, molds, and Clostridium. Natural fermentation is prone to spoilage, heat generation, protein degradation, and the production of butyric acid toxins. Spray 0.5% -1.5% weight ratio liquid formic acid on the harvested grass to quickly reduce the pH of silage to below 4.0, effectively inhibit the proliferation of spoilage microorganisms, and promote the benign fermentation of lactic acid bacteria in a targeted manner; 

Formic Acid Green | Shaanxi BLOOM Tech Co., Ltd

Livestock and poultry feed without acid resistant growth promoting agents

 

Formic Acid Feed | Shaanxi BLOOM Tech Co., Ltd

Young piglets and chicks have insufficient gastric acid secretion, and their intestines are prone to diarrhea caused by Escherichia coli and Salmonella. Add 0.3% -1.2% diluted liquid formic acid to the feed to dissociate hydrogen ions in the stomach, reduce intestinal pH, destroy harmful bacterial cell membrane structure, and promote targeted proliferation of probiotics such as lactic acid bacteria and bifidobacteria; Formic acid small molecules are easily absorbed, quickly supplying energy to animals, improving protein and mineral digestion and absorption rates by 8% -15%, completely replacing antibiotic growth promoters, in line with global anti drug policies; 

Improvement of aquaculture water bodies and preservation of feed
 

Spraying low concentration formic acid on fish and shrimp puffed pellet feed to inhibit mold growth and oil rancidity in feed storage; Regularly sprinkle a small amount of formic acid on the aquaculture pond to regulate the acidity and alkalinity of the water, decompose the residual feed, feces, ammonia nitrogen, and nitrite at the bottom of the pond, and improve the problem of black hair and odor on the bottom; Low salinity aquaculture specific acid-base buffering agents for South American white shrimp and salmon stabilize water pH fluctuations and reduce stress induced mortality.

Formic Acid Bodies | Shaanxi BLOOM Tech Co., Ltd

 

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