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Oxalic Acid Powder CAS 144-62-7
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Oxalic Acid Powder CAS 144-62-7

Oxalic Acid Powder CAS 144-62-7

Product Code: BM-3-1-002
English Name: oxalic acid
CAS No.: 144-62-7
Molecular formula: c2h2o4
Molecular weight: 90.03
EINECS No.: 205-634-3
Quality items: HPLC>99.0%, GC-MS
HS code: 29171110
Main market: USA, Australia, Brazil, Japan, Germany, Indonesia, UK, New Zealand , Canada etc.
Manufacturer: BLOOM TECH XI’an Factory
Technology service: R&D Dept.-5

Shaanxi BLOOM Tech Co., Ltd. is one of the most experienced manufacturers and suppliers of oxalic acid powder cas 144-62-7 in China. Welcome to wholesale bulk high quality oxalic acid powder cas 144-62-7 for sale here from our factory. Good service and reasonable price are available.

 

Oxalic acid powder is a kind of organic compound, which is a metabolic product of organisms, binary weak acid, widely distributed in plants, animals and fungi, and plays different functions in different organisms. Studies have found that more than 100 kinds of plants are rich in oxalic acid, especially oxalic acid spinach, amaranth, beet, purslane, taro, sweet potato and rhubarb. Because oxalic acid can reduce the bioavailability of mineral elements, it is easy to form calcium oxalate with calcium ions in the human body, resulting in kidney stones. Therefore, oxalic acid is often considered as an antagonist of mineral element absorption and utilization. Its anhydride is carbon trioxide.

product introduction

Chemical Formula

C2H2O4

Exact Mass

90

Molecular Weight

90

m/z

90 (100.0%), 91 (2.2%)

Elemental Analysis

C, 26.68; H, 2.24; O, 71.08

Morphological

liquid

Color

white

Melting point

189.5 ° C (Dec.) (lit.)

Boiling point

365.1 ° C (estimated)

Density

0.99 g / ml at 25 ° C

Storage conditions

store below + 30 ° C

solubility alcohol

solublesoluble 40 parts of solvent

Acidity coefficient ( pKa )

1.23 (at 25 ℃)

Flash point

101-157 ° C

Solubility H2O

0.002 mg / ml

Vapor density

< 0.01 mm Hg (20 ° C)

Refractive index

1.4261 (estimated)

Oxalic acid NMR | Shaanxi BLOOM Tech Co., Lt

Oxalic acid COA | Shaanxi BLOOM Tech Co., Lt

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Oxalic acid powder is an organic dicarboxylic acid with the chemical formula H2C2O4. It is the simplest dicarboxylic acid and widely exists in plants, animals, and microorganisms. It has a wide range of applications in multiple fields.

Oxalic acid industrial | Shaanxi BLOOM Tech Co., Lt

Industrial sector

(1) As a reducing agent and bleaching agent
Oxalic acid is often used as a reducing agent in industry, which can reduce some metal ions to metals and participate in the production of metals such as cobalt, nickel, and copper. In the process of metal extraction, oxalic aci can undergo chemical reactions with metal ions, reducing high valence metal ions to elemental metal, thereby achieving metal extraction and separation.

Meanwhile, oxalic aci is also an effective bleaching agent that can be used to bleach pulp, textiles, and other materials. During the pulp bleaching process, oxalic aci can remove colored impurities from the pulp, improving the whiteness and quality of the paper. In textile bleaching, oxalic acid can destroy the molecular structure of pigments in textiles, achieving the desired bleaching effect. In addition, oxalic aci can also be used in the production of catalysts, cleaning of metals and marble, and bleaching of textiles.

Oxalic acid materials | Shaanxi BLOOM Tech Co., Lt
Oxalic acid cleaning | Shaanxi BLOOM Tech Co., Lt

(2) Cleaning agent
Oxalic acid can chelate (bind) various metal ions and minerals, including calcium, magnesium, aluminum, etc., making it particularly suitable for removing lime scale and scale. In industrial equipment cleaning, oxalic aci can combine with calcium and magnesium ions on the surface of the equipment to form soluble oxalates, thereby dissolving and removing scale and lime, and restoring the normal operating efficiency of the equipment. For example, oxalic aci plays an important role in cleaning equipment such as boilers and heat exchangers.

(3) Dye industry
Oxalic acid can combine with certain chemicals to form dyes and act as a stabilizer for dyes, extending their lifespan. In the process of dye synthesis, oxalic aci can participate in chemical reactions and combine with other compounds to form dye molecules with specific colors. Meanwhile, oxalic acid can interact with certain functional groups in dye molecules, enhancing the stability of the dye and preventing it from decomposing or fading during storage and use.

Oxalic acid dye | Shaanxi BLOOM Tech Co., Lt
Oxalic acid industry | Shaanxi BLOOM Tech Co., Lt

(4) Photovoltaic industry
Oxalic acid can be used to manufacture silicon wafers for solar panels, helping to reduce surface defects on the wafers. In the production process of silicon wafers, oxalic aci can chemically treat the surface of silicon wafers to remove impurities and oxides, making the surface of silicon wafers smoother and more even. This can improve the photoelectric conversion efficiency of silicon wafers, reduce the reflection and scattering of light on the surface of silicon wafers, and thus enhance the performance of solar panels.

(5) Leather processing
Oxalic acid can be used as a tanning agent in leather processing. It can penetrate into leather fibers and react chemically with collagen in leather to form a stable cross-linked structure, making leather more stable and preventing decay and hardening. Leather tanned with oxalic acid has good softness, toughness, and wear resistance, which can meet the production needs of different leather products.

Oxalic acid leather | Shaanxi BLOOM Tech Co., Lt
Oxalic acid rust | Shaanxi BLOOM Tech Co., Lt

(6) Rust removal function
Oxalic acid has rust removal function and can be used for rust removal. Oxalic aci can combine with metal ions and react chemically with rust (mainly composed of iron oxide) to produce soluble iron oxalate, thereby removing rust from the metal surface. However, caution should be exercised when using oxalic aci. Oxalic aci has strong corrosiveness to stainless steel, and high concentrations of oxalic aci can easily corrode hands. The resulting acid oxalate has a high solubility but some toxicity.

Medical field

(1) Drug manufacturing
Oxalic aci is widely used in the pharmaceutical field and can be used to manufacture drugs such as streptomycin, oxytetracycline, tetracycline, streptomycin, borneol, vitamin B12, phenobarbital, etc. In the process of drug synthesis, oxalic aci can act as a reactant or catalyst, participate in chemical reactions, and promote the synthesis and conversion of drug molecules. For example, in the synthesis of streptomycin, oxalic acid can react with certain intermediates to form precursor compounds of streptomycin, which are further processed and purified to obtain the final drug product.

Oxalic acid field | Shaanxi BLOOM Tech Co., Lt
Oxalic acid pain | Shaanxi BLOOM Tech Co., Lt

(2) Acid resistance and pain relief
Oxalic acid has an antaci effect, which can inhibit the level of uric aci in the human body, help treat hyperuricemia and gout, and alleviate related symptoms. It can bind with uric aci in the body, reduce the concentration of uric aci, and decrease its deposition in joints and kidneys, thereby relieving pain and inflammation caused by gout. In addition, oxalic aci also has analgesic effects and can alleviate pain symptoms caused by diseases in patients. However, its specific analgesic mechanism is not fully understood and may be related to regulating neurotransmitter release or affecting inflammatory responses.

(3) Promote calcium absorption
Oxalic acid powder can combine with calcium to form easily absorbable calcium oxalate, thereby increasing the absorption rate of calcium and improving bone health. Under certain conditions, the combination of oxalic aci and calcium can form a stable oxalate calcium complex. This complex has relatively high solubility and absorption rate in the intestine, which can provide more calcium elements for the human body, help maintain normal bone growth and development, and prevent bone diseases such as osteoporosis.

Oxalic acid absorption | Shaanxi BLOOM Tech Co., Lt
Oxalic acid health | Shaanxi BLOOM Tech Co., Lt

(4) Improving cardiovascular health
Oxalic aci can regulate lipid metabolism, reduce cholesterol accumulation in the body, and help lower the incidence of cardiovascular disease. It can affect the synthesis, decomposition and transport of lipids in the body, reduce the level of low-density lipoprotein cholesterol (LDL-C) in the blood, and increase the level of high-density lipoprotein cholesterol (HDL-C), thus improving the blood lipid profile, reducing the risk of atherosclerosis, and protecting the health of the cardiovascular system.

Laboratory field

(1) Chemical reagents
Oxalic acid is an important chemical reagent in the laboratory, commonly used in the preparation of other chemicals such as oxalate esters, oxalate anhydrides, diethyl oxalate, sodium oxalate, etc. In organic synthesis experiments, oxalic aci can undergo esterification reactions with other alcohol compounds to generate various oxalate esters, which have wide applications in fields such as fragrances, coatings, plastics, etc. In addition, oxalic aci can also be used to prepare oxalic anhydride.

Oxalic acid field | Shaanxi BLOOM Tech Co., Lt
Oxalic acid uses | Shaanxi BLOOM Tech Co., Lt

Which is an important organic intermediate that can be used to synthesize various organic compounds.

(2) Participate in chemical reactions
Oxalic acid can serve as a reducing agent in the laboratory and participate in various chemical reactions. For example, it can cause the acidic potassium permanganate solution to fade and reduce it to divalent manganese ions, which is used as a method for determining the concentration of potassium permanganate in quantitative analysis. In chemical analysis, oxalic aci can also be used to precipitate metal ions such as calcium and magnesium, forming insoluble oxalate precipitates with these metal ions to achieve separation and determination of metal ions.

Environmental protection field

(1) Dealing with heavy metal pollution
Oxalic aci can combine with heavy metal ions to form soluble oxalate salts, which helps to remove heavy metal pollution. In industrial wastewater treatment, if the wastewater contains heavy metal ions such as lead, mercury, cadmium, etc., an appropriate amount of oxalic aci can be added to react the heavy metal ions with oxalic aci to form soluble oxalate.

Oxalic acid protection | Shaanxi BLOOM Tech Co., Lt
Oxalic acid gas | Shaanxi BLOOM Tech Co., Lt

Then, the heavy metal ions can be removed from the wastewater through precipitation, filtration, and other methods to achieve the goal of purifying the wastewater.

(2) Treating wastewater and exhaust gas
Oxalic acid powder can be used for the treatment of wastewater and exhaust gas, reducing the emission of pollutants. In wastewater treatment, oxalic acid can adjust the pH value of the wastewater to achieve suitable treatment conditions, and can also react chemically with certain organic pollutants in the wastewater to decompose them into harmless substances. In exhaust gas treatment, oxalic acid can absorb certain harmful gases such as sulfur dioxide, reducing the pollution of exhaust gas to the atmosphere.

Other fields

(1) Other fieldsFood processing (small application)
A small amount of oxalic aci can be used in food processing, such as bleaching or preservation, but the dosage needs to be strictly controlled. In terms of food bleaching, oxalic aci can remove pigments and impurities on the surface of food, improving the appearance quality of food. In terms of food preservation, oxalic aci has a certain antibacterial effect, which can inhibit the growth and reproduction of certain microorganisms and extend the shelf life of food.

Oxalic acid food | Shaanxi BLOOM Tech Co., Lt
Oxalic acid plant | Shaanxi BLOOM Tech Co., Lt

However, due to the toxicity of oxalic aci to the human body, its use in food processing is strictly restricted and regulated.

(2) Plant extraction process
Partial plant extraction processes utilize oxalic aci to dissolve impurities and purify target components. During the extraction process of plant active ingredients, plants often contain impurities such as cellulose, hemicellulose, lignin, etc. Oxalic acid can undergo chemical reactions with these impurities, causing them to dissolve in the extraction solvent, thereby achieving the separation of target components from impurities, improving the purity and extraction efficiency of target components.

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The industrial production methods of oxalic acid mainly include sodium formate method, oxidation method, carbonyl synthesis method, ethylene glycol oxidation method, propylene oxidation method, and carbon monoxide coupling method.

1. Sodium formate method:

After carbon monoxide purification, it reacts with sodium hydroxide under pressure to produce sodium formate, which is then dehydrogenated at high temperature to produce sodium oxalate. Sodium oxalate is then subjected to lead (or calcification), acidification, crystallization, dehydration and drying processes to obtain the finished oxalic acid. The synthesis pressure of carbon monoxide and sodium hydroxide is generally 1.8-2.0 MPa. The dehydrogenation temperature is 400 ℃.

Oxalic acid synthesis | Shaanxi BLOOM Tech Co., Lt

2. Oxidation method:

Using starch or glucose mother liquor as raw materials, oxalic acid is obtained by oxidation reaction with nitric acid sulfuric acid in the presence of alum catalyst. The nitrogen oxides in the exhaust gas are sent to the absorption tower for recovery to generate dilute nitric acid.

Oxalic acid synthesis | Shaanxi BLOOM Tech Co., Lt

3. Carbonylation synthesis method:

Carbon monoxide is purified to over 90% and undergoes carbonylation reaction with butanol in the presence of palladium catalyst to produce dibutyl oxalate, which is then hydrolyzed to obtain oxalic acid. This method is divided into liquid-phase and gas-phase methods, with lower reaction conditions and a reaction pressure of 300-400 kPa. The reaction pressure of liquid-phase method is 13.0-15.0 MPa.

Oxalic acid synthesis | Shaanxi BLOOM Tech Co., Lt

4. Ethylene glycol oxidation method:

Ethylene glycol is used as the raw material and oxidized with air in the presence of nitric acid and sulfuric acid.

5. Acrylic oxidation method:

The oxidation process is carried out in two steps. The first step is to oxidize propylene with nitric acid to convert it into alpha nitrolactic acid; Then further catalytic oxidation is carried out to obtain oxalic acid. The second step can also use mixed acids as oxidants. The propylene oxidation method produces industrial grade oxalic acid dihydrate compounds with a total yield of over 90% based on propylene.

Raw material consumption quota: 510 kg/t for coke (84%), 950 kg/t for sulfuric acid (100%), and 920 kg/t for caustic soda (100%).

Oxalic acid synthesis | Shaanxi BLOOM Tech Co., Lt

Oxalic acid powder usually exists in the form of salt in many plant cell membranes in nature. In the past, in industry, wood chips and strong alkali were melted together at 240-250 ℃ to first produce oxalate, which was then acidified to obtain oxalic acid. Later, the sodium formate dehydrogenation method was used to produce oxalic acid. In industry, carbon monoxide (such as tail gas from yellow phosphorus production) is absorbed by caustic soda to produce sodium formate. The latter is dehydrogenated at 380 ℃ to obtain sodium oxalate, which is then treated with lime and sulfuric acid to produce oxalic acid.

FAQ
 

What happens if we eat oxalic acid?

While oxalic acid is a normal end product of mammalian metabolism, the consumption of additional oxalic acid may cause stone formation in the urinary tract when the acid is excreted in the urine. Soaking and cooking of foodstuffs high in oxalate will reduce the oxalate content by leaching.

Is oxalic acid the same as vinegar?

Oxalic acid is a strong, specialized cleaner ideal for heavy rust, mineral stains, and wood bleaching, while vinegar is a mild, safe household acid better for light cleaning and descaling. Oxalic acid acts faster but requires caution (toxic, irritant), whereas vinegar is safe and versatile for everyday use.

Is oxalic acid found in tomatoes or not?

Yes, oxalic acid is present in tomatoes. Tomatoes contain a low to moderate amount, typically around 50 mg of oxalic acid per 100g serving. While citric and malic acids are also present, oxalic acid is recognized as one of the organic acids naturally occurring in tomatoes.

What does oxalic acid do for the body?

Oxalic acid is a toxic compound found in many plants that, when ingested in high amounts or concentrated forms, can cause severe poisoning, including acute kidney failure, mouth/throat burns, vomiting, and convulsions. It binds with calcium in the body to form calcium oxalate crystals, which can cause kidney damage, kidney stones, and reduced nutrient absorption.

 

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