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Butyldiglycol is an organic compound with the molecular formula C8H18O3, HO(CH2 ) 2O ( CH2 ) 2O ( CH2 ) 3ch3, It is a colorless and transparent liquid with a slight smell of butanol. It can be mixed with water in any proportion and dissolved in various organic solvents such as ethanol, ether, and oil. It is commonly used as a solvent for nitrocellulose, varnish, printing ink, oil, resin, etc., and is an intermediate in the synthesis of plastics. Diethylene glycol butyl ether also has its unique value as various aerosol propellants in hair care, skincare, pharmaceuticals, and coatings. In addition, it also plays an important role as a stabilizer for latex paint, an evaporation inhibitor for aircraft coatings, and a surface processing modifier for high-temperature baked enamel paint. In organic synthesis, it is often used as an intermediate for plasticizers and a diluent for hydraulic brake fluids. In addition, it is also used in the production of piperonyl butoxide compounds.

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Chemical Formula |
C8H18O3 |
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Exact Mass |
162 |
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Molecular Weight |
162 |
|
m/z |
162 (100.0%), 163 (8.7%) |
|
Elemental Analysis |
C, 59.23; H, 11.18; O, 29.59 |
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Butyldiglycol (DEGB) is a colorless, volatile liquid with a slight aromatic odor. Its chemical formula is C8H18O3, which is an important organic solvent. Due to its unique physical and chemical properties, it has a wide range of applications in coatings, dyes, resins, and other fields.
Solvent
Dissolving resin and natural rubber: It is a good solvent that can dissolve various resins and natural rubber, such as epoxy resin, polyurethane resin, acrylic resin, etc. Adding it to the coating can improve its solubility, make it more uniform, and thus enhance the performance and quality of the coating.
Adjusting volatilization rate: With a lower boiling point and a higher volatilization rate, it can adjust the volatilization rate of coatings or paints to make them more controllable.
This is very important for construction in humid or rainy weather to avoid the problem of paint drying too slowly or too quickly.
Volatility: It has low volatility and can reduce the impact of coatings or paints on the environment during use.
Improve leveling: With lower surface tension, it can improve the leveling of coatings or paints and reduce surface defects such as shrinkage. This is very important for the decorative effect of coatings, as it can ensure the smoothness and flatness of the coating.
Antistatic performance: It has good anti-static performance, which can reduce the electrostatic adsorption on the surface of coatings or paints, making the coating smoother.
Adjusting odor: It has a slight aromatic odor and can adjust the odor of coatings or paints to make them more pleasant.
Chemical stability: It has high chemical stability and can ensure that the coating or paint is not easily deteriorated during use.
Coating additives
Stabilizer for latex paint: It can be used as a stabilizer for latex paint to improve its stability and dispersibility, and prevent problems such as delamination and precipitation during storage and use.
Aircraft paint evaporation inhibitor: added to aircraft paint, it can inhibit the evaporation of paint, extend the service life of paint, and improve the adhesion and durability of paint.
Surface processing improver for high-temperature baked enamel paint: It can be used as a surface processing improver for high-temperature baked enamel paint, improving the surface gloss and hardness of the enamel paint, enhancing the decorative effect and service life of the enamel paint.
Specific examples
Automotive paint: Adding it to automotive paint can improve the leveling and glossiness of the paint, making the surface of the car smoother and brighter. At the same time, the evaporation rate of the coating can be adjusted to make it more uniform during the drying process, avoiding problems such as uneven drying and cracking.

Architectural coatings: Adding them to architectural coatings can improve their construction performance and decorative effect. For example, adding it to interior and exterior wall coatings can improve their adhesion and water resistance, making them more durable and aesthetically pleasing.
Wood coatings: Adding wood coatings can improve the transparency and glossiness of the coatings, making the surface of the wood more natural and shiny. At the same time, it can also prevent problems such as cracks and peeling on the surface of wooden objects.
Application in dyes
(1) Dissolved dye
Solubility: It has good solubility and can dissolve various dyes, such as dispersed dyes, reactive dyes, acid dyes, etc. Adding it during the dye preparation process can improve the solubility and dispersibility of the dye, making it more uniform and stable.
(2) Dye additives
Dispersant: It can be used as a dispersant for dyes to improve their dispersibility and stability in solution. This is very important for the dyeing effect and uniformity of dyes.
Emulsifier: It is added during the dye preparation process and can also be used as an emulsifier to make the dye more evenly dispersed in the solution, improving the dyeing effect and uniformity of the dye.
Specific examples
Textile dyes: Adding them to textile dyes can increase their solubility and dispersibility, allowing them to penetrate fibers more evenly and improve dyeing efficiency and uniformity. At the same time, it can also prevent problems such as sedimentation and clumping of dyes during the dyeing process.

Leather dye: Adding it to leather dye can improve the permeability and uniformity of the dye, making the leather surface more vivid and shiny. At the same time, it can also prevent problems such as cracking and peeling of dyes during the dyeing process.
Paper dye: Adding it to paper dye can increase its solubility and dispersibility, making the dye more evenly adhere to the surface of the paper and improving the dyeing effect and uniformity. At the same time, it can also prevent uneven penetration and color distribution of dyes during the dyeing process.
Application in resin
(1) Dissolve resin
Solubility: It can dissolve various resins, such as epoxy resin, polyurethane resin, acrylic resin, etc. Adding it during the resin preparation process can improve the solubility and dispersibility of the resin, making it more uniform and stable.
(2) Resin additives
Plasticizer: It can serve as an intermediate for plasticizers and is used in the production of various plastic and rubber products. Adding it to resin can improve its flexibility and plasticity, making it easier to process and shape.
Diluent: It is added during the resin preparation process and can also be used as a diluent to reduce the viscosity of the resin, making it easier to apply and process. This is very important for the processing performance and finished product quality of the resin.
Specific examples
Epoxy resin: Adding diethylene glycol butyl ether to epoxy resin can improve its flexibility and plasticity, making it easier to process and shape. At the same time, it can also serve as a solvent and diluent for epoxy resin, reducing its viscosity and improving its coating and processing properties.
Polyurethane resin: Adding it to polyurethane resin can improve its flexibility and wear resistance, making it more suitable for making various elastomers and sealing materials.
Meanwhile, it can also serve as a solvent and diluent for polyurethane resin, reducing its viscosity and improving its processing performance and finished product quality.
Acrylic resin: Adding it to acrylic resin can improve its transparency and glossiness, making butyldiglycol more suitable for making various coatings and inks. At the same time, it can also serve as a solvent and diluent for acrylic resin, reducing its viscosity and improving its coating and processing properties.
Applications in other fields
(1) Lubricant
Metal processing lubricant: can be used as a metal processing lubricant to reduce friction and wear between metal parts, improve metal processing efficiency and finished product quality.
Hydraulic brake fluid diluent: Adding it to the hydraulic brake fluid can reduce its viscosity, improve its fluidity and lubricity, thereby enhancing the performance and stability of the hydraulic brake.
(2) Cleaning agent
Metal detergent: can be used as a metal detergent to clean oil and impurities on metal surfaces, improve the cleanliness and smoothness of metal surfaces.
Paint remover: Adding paint remover can improve its solubility and permeability, making it easier to remove paint and coatings from metal surfaces.
(3) Drug extractant
Drug extraction: It can be used as a drug extraction agent to extract the active ingredients in drugs, improve the purity and quality of drugs.
Other applications
Fuel additive: can be used as a fuel additive to improve the combustion efficiency and octane value of fuel, reduce fuel emissions and pollution.
Cosmetics: Adding them to cosmetics can improve their solubility and stability, making them easier to apply and absorb.
Pepper based butoxide compounds: are important raw materials for the production of pepper based butoxide compounds.

According to literatures and patents, there are mainly two ways to synthesize butyldiglycol:
Ethylene glycol butyl ether is prepared from ethylene oxide and butanol:
CH3CH2CH2CH2OH→HOCH2CH2OCH2CH2CH2CH3
Zhang Mu used this reaction route to prepare ethylene glycol butyl ether in the supplement of petrochemicals Vol. 37 in 2008. In this method, ethylene oxide and n-butanol were used as raw materials, and heteropoly acid was used as catalyst to prepare ethylene glycol butyl ether at low pressure of 70-120 ℃. The selectivity of ethylene glycol butyl ether was up to 75%. However, this reaction has many by-products and is a strong exothermic reaction. The reaction is not easy to control. The product contains a large amount of diethylene glycol butyl ether, triethylene glycol butyl ether, tetraethylene glycol butyl ether, pentaethylene glycol butyl ether, hexaethylene glycol butyl ether and the corresponding diether. Subsequent separation is difficult and energy consumption is high.

Synthesis of ethylene glycol butyl ether from synthesis gas and formaldehyde
CO+2H2+HCHO+CH3CH2CH2CH2OH→HOCH2CH2OCH2CH2CH2CH3+H2O
In the United States Patent 4071568, Kurashiki, a Japanese chemist, introduced the synthesis of ethylene glycol butyl ether with synthesis gas, formaldehyde and n-butanol as raw materials and cobalt as catalyst under the extremely high pressure of 100-250 ℃, 50MPa, of which the yield of ethylene glycol butyl ether is the highest, 55.6%. However, the disadvantages of this method are that the reaction needs to be carried out under extremely high pressure, requiring 500 atmospheres, requiring extremely high requirements for reaction equipment, and the preparation process of the cobalt catalyst for the reaction is cumbersome and cannot be reused, so it is not used in large-scale industrial production.
A new synthesis route of ethylene glycol butyl ether, the first step is the highly selective synthesis of butoxymethoxymethane from methylal and butanol; The second step is the directional carbonylation of butoxymethoxymethane to produce methyl butoxyacetate; The third step is the hydrogenation of methyl butoxyacetate to produce ethylene glycol butyl ether and methanol. Among them, the third step of ester hydrogenation reaction is very easy and has high selectivity. The second step is the directional carbonylation reaction. It has been reported in the literature and patents that the carbonylation of methylal produces methyl methoxyacetate with high selectivity. Only for the synthesis of the first reaction raw material methoxybutoxymethane, there is no report on the specific synthesis method and route on SciFinder.
HOCH2CH2OH+CH3CH2CH2CH2OH→HOCH2CH2OCH2CH2CH2CH3
FAQ
What is butyl diglycol used for?
What is Butyl Di Glycol used for? Butyl di glycol is most commonly used in the coatings and paint industries where its low volatility and high boiling point have seen it widely accepted as a flow promoter for baking finishes such as melamine, urea, phenol, or epoxy resin composites.
What is butyl glycol?
Butyl Glycol, or BG, is a colourless liquid with a sweet, ether-like odour. It is derived from the family of glycol ethers and is a butyl ether of ethylene glycol. It is a fast-evaporating solvent with an excellent balance of hydrophilic and hydrophobic character; excellent active solvency and coupling properties.
What is DPNB solvent used for?
Glycol Ether DPNB is a colorless liquid with a mild odor and low volatility. It has low water solubility, good coupling and demonstrates good solvency for coating resins. The properties of DPNB support its use in agricultural, coating, cleaning, ink, textile, and adhesive products.
What is another name for butyl triglycol?
Butyl tri glycol (also known as BTGE, butyl tri tetra, triethylene glycol butyl ether, butoxy triglycol and triglycol monobutyl ether) is a clear, colourless liquid with a mild odour and the formula C10H22O4 / CH3(CH2)3(OCH2CH2)3OH.
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