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Dimethyl phthalate(dmp) is an organic compound with the molecular formula C10H10O4 and a molecular weight of 194.19, CAS 131-11-3. It is a colorless, transparent, slightly yellow oily liquid with a slight aromatic odor. It is miscible with general organic solvents such as ethanol and ether, but insoluble in water and petroleum ether.
Used as a gas chromatography stationary phase; This product is a plasticizer with strong solubility in various resins. It can be mixed with various cellulose resins, rubber, and vinyl resins, and has good film-forming, adhesive, and waterproof properties. Often used in combination with diethyl phthalate to produce cellulose acetate film, varnish, transparent paper, molding powder, etc., with a small amount used for the production of nitrocellulose. It can also be used as a plasticizer for nitrile rubber. This product can also be used as a solvent for mosquito oil (crude oil), polyvinyl fluoride paint, methyl ethyl ketone peroxide, and DDT.

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Chemical Formula |
C10H10O4 |
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Exact Mass |
194 |
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Molecular Weight |
194 |
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m/z |
194 (100.0%), 195 (10.8%) |
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Elemental Analysis |
C, 61.85; H, 5.19; O, 32.96 |
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Dimethyl phthalate (DMP) is an important organic compound with the chemical formula C10H10O4 and a molecular weight of 194.19. It is a colorless, transparent, slightly yellow oily liquid with an aromatic aroma. It is miscible with organic solvents such as ethanol and ether, but insoluble in water and petroleum ether. Due to its excellent solubility, film-forming ability, adhesiveness, and waterproofness, DMP has a wide range of applications in multiple fields.

Application of plasticizers
Plastics:Dimethyl phthalate(dmp) is an efficient plasticizer with strong solubility for various resins, such as cellulose resin, rubber, vinyl resin, etc. In plastic products, DMP can significantly improve the flexibility and toughness of materials, reduce processing temperature, and improve processing performance. For example, in polyvinyl chloride (PVC) products, the addition of DMP can increase the flexibility and durability of the material, and is widely used in plastic films, pipes, fittings, and other fields.
The plasticizing mechanism of DMP is mainly based on the interaction between the ester groups in its molecular structure and the resin molecular chains. The ester groups in DMP molecules can form hydrogen bonds or van der Waals forces with polar groups in the resin molecular chains, thereby weakening the interaction forces between resin molecular chains, making them easier to slide, and improving the plasticity of the material.


Synthetic leather and coatings:
In the production process of synthetic leather, DMP acts as a soluble solvent, giving synthetic leather good softness and wear resistance. Meanwhile, DMP can also serve as a plasticizer and thickener for coatings, improving their film-forming, adhesive, and waterproof properties. For example, in cellulose acetate varnish, the amount of DMP can reach 75%, making the paint film soft and waterproof.
The application of DMP in coatings is also reflected in its synergistic effect with other plasticizers. By using plasticizers such as diethyl phthalate (DEP) in combination, the disadvantages of high volatility and low temperature crystallization of DMP can be overcome, and the comprehensive performance of the coating can be improved.


Application of solvents and diluents
Nitrocellulose and resin:DMP performs well in the dissolution of nitrocellulose and resin. It can be compatible with nitrocellulose to obtain products with high strength, good light resistance, and no odor. Meanwhile, DMP can also serve as a solvent for resin processing and molding. For example, in the production of cellulose acetate films, varnishes, transparent paper, and molding powders, DMP is often used in conjunction with DEP to improve the performance of the products.
The advantage of DMP as a solvent lies in its good solubility and volatility. It can quickly dissolve resin at lower temperatures and is prone to volatilization during processing, without affecting the final performance of the product.
Coatings and inks
DMP has a wide range of applications in the fields of coatings and inks. It can be used as a diluent for solvent based coatings and inks, providing good solubility and fluidity.


Meanwhile, DMP can also improve the adhesion and durability of coatings and inks. For example, in inkjet printing ink, the addition of DMP can make the printing effect clearer and more durable.
The application of DMP in coatings and inks is also reflected in its synergistic effect with other solvents. By mixing with other solvents, the viscosity, drying speed, and glossiness of coatings and inks can be adjusted.
Application of pharmaceuticals and personal care products
Medical equipment:DMP has important applications in the field of medical devices. It can be used as a raw material for manufacturing medical tapes, medical packaging materials, medical syringes and other medical devices. The addition of DMP can improve the flexibility and durability of medical devices, while ensuring the safety and hygiene of the products.

In the production of medical tape, DMP as a plasticizer can improve the adhesion and flexibility of the tape, making it easier to adhere to the skin and less prone to detachment. In the production of medical packaging materials, the addition of DMP can improve the waterproof and barrier properties of the material, protecting medical devices from external pollution.
Personal care products:DMP is also widely used in personal care products. It can be used as one of the ingredients of personal care products such as perfume and essence, giving the product good stability and ductility. Meanwhile, DMP can also serve as a moisturizer and softener for skincare products, enhancing the user experience of the product.


In the production of perfume, DMP can be used as a solvent to dissolve essence components and make them evenly dispersed in the matrix. In the production of skincare products, the addition of DMP can increase the moisturizing and smooth feeling of the product, and improve user satisfaction.
Mosquito repellents and pesticide applications
Anophelifuge:DMP is a broad-spectrum and highly effective insect repellent. It has a repellent effect on blood sucking insects such as mosquitoes, sandflies, midges, and black flies, with an effective repellent time of 2-4 hours. The advantage of DMP as a mosquito repellent lies in its low toxicity, low irritation, and long-lasting effect.

The mosquito repellent mechanism of DMP is mainly based on the interaction between ester groups in its molecular structure and insect olfactory receptors. DMP molecules can simulate the odor of insect pheromones, interfere with the insect's olfactory system, and make it impossible to locate the host. At the same time, DMP also has a certain degree of volatility and can form a protective film on the surface of the skin, continuously exerting its mosquito repellent effect.
Pesticide solvents:
DMP can also be used as a solvent and adjuvant for pesticides. It can dissolve pesticide active ingredients, improve the dispersibility and adhesion of pesticides. At the same time, DMP can also adjust the viscosity and drying speed of pesticides, improving the effectiveness of pesticide use.


In the process of pesticide formulation, the addition of DMP can reduce the surface tension of pesticides, making them easier to wet and penetrate plant leaves. At the same time, DMP can also form a stable lotion or suspension with the active ingredients of pesticides to improve the stability and durability of pesticides.
Other special applications
GS stationary liquid:Dimethyl phthalate(dmp) can be used as a gas chromatography stationary phase. It has good thermal and chemical stability, and can maintain stable performance at high temperatures. Meanwhile, DMP has the ability to separate various organic compounds and can be used to analyze organic components in complex samples.


In gas chromatography analysis, DMP can be coated on the inner wall of the chromatographic column as a stationary liquid, forming a uniform liquid film. When the sample passes through the chromatographic column, the distribution coefficients of different components between the stationary liquid and the mobile phase are different, thus achieving separation.
Fluorescent rod solvent:
DMP can also serve as a solvent for fluorescent rods. A fluorescent stick is a toy or emergency lighting tool that uses chemical reactions to emit light. DMP, as a solvent, can dissolve fluorescent dyes and oxidants, allowing them to mix evenly and undergo chemical reactions to produce light.


In the production of fluorescent sticks, the addition of DMP can adjust the concentration and reaction rate of fluorescent dyes, thereby controlling the luminescence intensity and duration of the fluorescent sticks. At the same time, DMP can also improve the safety and stability of fluorescent rods, preventing accidents such as leaks and explosions.
Insulation paint and varnish:
DMP is also used in the production of insulating paints and varnishes. It can be used as a solvent and plasticizer to improve the flexibility and adhesion of the paint film. At the same time, DMP can also increase the waterproof and corrosion-resistant properties of the paint film, protecting electrical equipment from external

environmental erosion.
In the production of insulating paint, the addition of DMP can reduce the viscosity of the paint and improve its workability. In the production of varnish, the addition of DMP can make the paint film smoother and brighter, improving the decorative quality of the product.

A preparation method of dimethyl phthalate(dmp) includes the following steps:
1. Add the raw material phthalic anhydride and excess methanol into the reactor, add concentrated sulfuric acid as the catalyst, control the temperature in the reactor at 0~150 ℃, and react for 16-20 hours. After the reaction, neutralize the catalyst and unreacted phthalic anhydride with alkali solution.
2. Let it stand for layering, and then wash it with clean water for several times. After the wastewater containing alcohol is collected, use the recovery tower to recover the alcohol for recycling. Heat the lower ester layer after layering, and flush the alcohol under reduced pressure (use the high gravity bed to recover the methanol for recycling). Add active carbon to decolorize it, and then filter it through the plate and frame filter press to obtain the finished product of dimethyl phthalate.
The invention uses excessive alcohol as the water carrying agent to gradually carry out the esterification reaction to the end, simplifies the process, and has good product quality Compared with the distillation process of distillation tower, this process uses high gravity bed to recover methanol, which effectively reduces energy consumption and has better environmental significance.

Dimethyl phthalate is sensitive to light and is not easy to see light for a long time. This dimethyl phthalate(dmp) should be stored in a cool, dry and ventilated place to prevent physical deterioration; It shall be stored separately from incompatible substances. Empty containers may contain residual steam and liquid, and may also be dangerous. When the product is heated and the temperature reaches above the flash point, it is easy to cause fire and can form explosive air mixtures. Dimethyl phthalate is degraded by heat to produce carbon monoxide and carbon dioxide. Under normal laboratory conditions, the acetone, dimethyl sulfoxide, ethanol (95%) and aqueous solution of this product are stable within 24 hours.
Frequently Asked Questions
What is dmp chemical used for?
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Found within many consumer products, phthalates are industrial plasticizers that impart flexibility and resilience to plastic, among other uses. Dimethyl phthalate (DMP) is used in insect repellant, plastic, and as a rocket propellant .
Is DMP a drug?
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N,N-dimethylpentylone (DMP) is a synthetic cathinone. Synthetic cathinones are stimulants that may have similar effects to MDMA. Cathinones can significantly affect body temperature regulation and increase the risk of cardiac events (e.g. heart attack) and neurotoxicity.
Is DMP soluble in water?
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DMP is slightly soluble in water, and as a weak acid (pka-10.6), it is also soluble in alkaline solutions (Sober, 1970). 2,4-DMP is easily soluble in organic solvents such as alcohols and ethers.
Dipolar aprotic solvent health hazards
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Although the benefits of DMF are significant, it's reproductive toxicity is well established. Damage to the liver is another health concern associated with exposure to DMF. This has led to regulatory action being implemented to restrict the use of DMF.
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