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4,4'-Methylenedianiline CAS 101-77-9
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4,4'-Methylenedianiline CAS 101-77-9

4,4'-Methylenedianiline CAS 101-77-9

Product Code: BM-3-2-060
English Name: 4,4'-Methylenedianiline
CAS No.: 101-77-9
Molecular formula: c13h14n2
Molecular weight: 198.26
EINECS No.: 202-974-4
MDL No.:MFCD00007914
Hs code: 28273985
Analysis items: HPLC>99.0%, LC-MS
Main market: USA, Australia, Brazil, Japan, Germany, Indonesia, UK, New Zealand , Canada etc.
Manufacturer: BLOOM TECH Changzhou Factory
Technology service: R&D Dept.-4

Shaanxi BLOOM Tech Co., Ltd. is one of the most experienced manufacturers and suppliers of 4,4'-methylenedianiline cas 101-77-9 in China. Welcome to wholesale bulk high quality 4,4'-methylenedianiline cas 101-77-9 for sale here from our factory. Good service and reasonable price are available.

 

4,4'-Methylenedianiline also known as MDA, CAS 101-77-9, molecular formula C13H14N2, is a light yellow crystal that turns black when exposed to light. Difficult to dissolve in water, easily soluble in ethanol, ether, and benzene. Used for adhesives, laminates, and coatings. It can also be used as a vulcanization accelerator for hydrogenated butadiene rubber and latex, as well as a thiazole accelerator and activator in natural rubber and styrene butadiene rubber. It is also used in the production of diisocyanates, polyamides, etc.

Product Introduction

As an important organic chemical intermediate, it plays a crucial role in various fields such as rubber industry, insulation materials, dye industry, organic synthesis, resin curing agents, heat-resistant polymers and polyisocyanate monomers, analytical reagents, and other special applications.

Chemical Formula

C13H14N2

Exact Mass

198

Molecular Weight

198

m/z

198 (100.0%), 199 (14.1%)

Elemental Analysis

C, 78.75; H, 7.12; N, 14.13

CAS 101-77-9 4,4'-Methylenedianiline | Shaanxi BLOOM Tech Co., Ltd

4,4'-Methylenedianiline | Shaanxi BLOOM Tech Co., Ltd

Manufacture Information

Synthesis of 4,4'-Methylenedianiline:
 

Firstly, cool the hydrochloric acid, water, and newly evaporated aniline while stirring.

 

Then add formaldehyde solution and heat the reaction. The reaction product is 4,4 '- diaminophenylmethane hydrochloride.

 

After neutralizing and alkalizing the reaction product with sodium carbonate solution, steam distillation is carried out until there is no aniline in the components.

 

Finally, dissolve a small amount of hydrochloric acid in the precipitate, gradually precipitate with dilute ammonia water, and filter the resin like substance of the first precipitate. Excess ammonia water is added to the filtrate to obtain a white crystalline precipitate, which is then filtered to produce the product.

 

Further purification can be achieved through recrystallization of ethanol or water.

Chemical

Usage

4,4'-Methylenedianiline (MDA), as an important organic chemical intermediate, plays a crucial role in multiple industrial fields. Its unique chemical properties and structure make it the cornerstone for manufacturing various high-performance materias and chemicals. This article will cover rubber industry, insulation materias, dye industry, organic synthesis, resin curing agents, heat-resistant polymers and polyisocyanate monomers, analytical reagents, and other special applications.

4,4'-Methylenedianiline rubber | Shaanxi BLOOM Tech Co., Ltd

Key role in the rubber industry

In the rubber industry, it is an indispensable additive. It is mainly used as a vulcanization accelerator and antioxidant to enhance the performance and stability of rubber products.

1. Vulcanization accelerator
In the process of rubber vulcanization, it can accelerate the vulcanization reaction, shorten the vulcanization time, and improve the vulcanization efficiency.

This characteristic enables rubber products to achieve the required physical and chemical properties faster during the production process, thereby improving production efficiency. In addition, it can improve the adhesion performance between rubber and metal skeleton, and enhance the structural strength of rubber products.

2. Antioxidants
Rubber products are easily corroded by oxidizing substances such as oxygen and ozone during use, leading to performance degradation or even failure. As an effective antioxidant, it can delay the aging process of rubber and extend the service life of rubber products.

4,4'-Methylenedianiline process | Shaanxi BLOOM Tech Co., Ltd
4,4'-Methylenedianiline varieties | Shaanxi BLOOM Tech Co., Ltd

It is particularly suitable for rubber products such as tires, sidewalls, ply cords, inner tubes, conveyor tubes, rubber hoses, and V-belts, providing long-lasting protection for these products.

3. Application of rubber varieties
In synthetic rubber such as natural rubber and styrene butadiene rubber, as a thiazole promoter and activator, it can significantly improve the processing performance of rubber and the physical properties of the final product. It can also serve as an antioxidant and anti-aging agent for special rubbers such as chloroprene rubber and butyl rubber, enhancing their weather resistance and chemical corrosion resistance.

Core raw materials for insulation material manufacturing

It also occupies an important position in the field of insulation materia manufacturing. It is mainly used for producing high-performance insulation paints, laminates, adhesives, etc.

1. Insulation paint
The insulation paint synthesized using it has excellent heat resistance, insulation properties, and mechanical properties. These insulating paints are widely used in the insulation treatment of electrical equipment such as motors, transformers, wires and cables.

4,4'-Methylenedianiline materials | Shaanxi BLOOM Tech Co., Ltd
4,4'-Methylenedianiline board | Shaanxi BLOOM Tech Co., Ltd

Which can effectively prevent current leakage and short circuit accidents. They can also withstand long-term operation in high-temperature environments, ensuring the stability and safety of electrical equipment.

2. Laminated board
In laminated board manufacturing, as an important component of resin curing agent, it can enhance the interlayer adhesion and overall strength of laminated boards. These laminates have excellent electrical and mechanical properties, making them suitable for producing high-performance insulation materias such as electrical insulation laminates and motor liners.

They have broad application prospects in fields such as aerospace, electronics, and electrical appliances.

3. Adhesive
It can also be used to prepare high-performance H-grade adhesives. These adhesives have excellent heat resistance, bonding strength, and chemical corrosion resistance, which can meet the bonding needs under extreme conditions such as high temperature and high pressure. They play an important role in fields such as aerospace and automotive manufacturing, providing reliable bonding solutions for these industries.

4,4'-Methylenedianiline electrical | Shaanxi BLOOM Tech Co., Ltd
4,4'-Methylenedianiline dye | Shaanxi BLOOM Tech Co., Ltd

Important raw materials for the dye industry

In the dye industry, it is an important intermediate raw materia. It is mainly used for synthesizing high-performance dye products such as azo dyes.

1. Synthesis of azo dyes
Azo dyes are an important class of synthetic dyes with advantages such as bright color and good fastness. As a key raw materia in the synthesis of azo dyes, it can react with various coupling components to generate azo dyes with specific colors. These dyes are widely used in the coloring process of industries such as textiles, leather, and papermaking, providing a wide range of color choices for these industries.

2. Improvement of dye performance
By introducing high-performance intermediate materias such as 4,4 '- diaminodiphenylmethane, the color vividness, fastness, and weather resistance of azo dyes can be significantly improved. This makes these dyes have broader application prospects in high-end textiles, outdoor products, and other fields. They can also meet the requirements of environmental regulations and reduce the harm to the environment and human health.

4,4'-Methylenedianiline outdoor | Shaanxi BLOOM Tech Co., Ltd
4,4'-Methylenedianiline field | Shaanxi BLOOM Tech Co., Ltd

Multifunctional intermediates in the field of organic synthesis

In the field of organic synthesis, it is a highly valuable multifunctional intermediate. It can participate in various organic reactions to synthesize organic compounds with specific structures and properties.

1. Polyamide synthesis
High performance polyamide materias can be synthesized using 4,4 '- diaminodiphenylmethane. These polyamide materias have excellent mechanical properties, heat resistance, and chemical corrosion resistance, and are widely used in fields such as aerospace, automotive manufacturing, electronics, and electrical appliances.

They can withstand long-term operation under extreme conditions such as high temperature and high pressure, providing reliable materia support for these industries.

2. Preparation of corrosion inhibitors
4,4'-Methylenedianiline can also be used to prepare chemicals such as corrosion inhibitors. These corrosion inhibitors can inhibit the corrosion rate of metals in corrosive media and extend the service life of metal equipment.

4,4'-Methylenedianiline industry | Shaanxi BLOOM Tech Co., Ltd
4,4'-Methylenedianiline uses | Shaanxi BLOOM Tech Co., Ltd

They have broad application prospects in fields such as petrochemicals and marine engineering, providing effective anti-corrosion solutions for these industries.

3. Synthesis of other organic compounds
In addition to the aforementioned applications, it can also be used for synthesizing various other organic compounds. For example, it can be used as an important raw materia for synthesizing certain pharmaceutical intermediates, pesticide raw materias, etc. These organic compounds play an important role in fields such as medicine and pesticides, providing strong guarantees for human health and agricultural production.

Key components of resin curing agent

In the field of resin curing agents, it also occupies an important position. It is mainly used in the curing process of thermosetting resins such as epoxy resins.
1. Curing of epoxy resin
Epoxy resin is an important thermosetting resin with excellent adhesion, chemical corrosion resistance, and mechanical properties. During the curing process of epoxy resin, as an important component of the curing agent, it can undergo chemical reactions with the epoxy resin to form a three-dimensional network structure of polymer compounds.

4,4'-Methylenedianiline epoxy | Shaanxi BLOOM Tech Co., Ltd
4,4'-Methylenedianiline coating | Shaanxi BLOOM Tech Co., Ltd

This cured product has excellent physical and chemical properties and is widely used in fields such as coatings, adhesives, and composite materias.

2. Optimization of curing performance
By adjusting the dosage and curing conditions, the curing performance of epoxy resin can be optimized. For example, increasing the amount of curing agent can improve the crosslinking density and hardness of the cured product; Raising the curing temperature can accelerate the curing reaction rate and shorten the curing time. These optimization measures can meet the performance requirements of epoxy resin in different application scenarios.

3. Expansion of application fields
With the advancement of technology and the development of industry, the application fields of epoxy resin are constantly expanding. As a key component of epoxy resin curing agents, it will also play an important role in more fields. For example, in the aerospace field, high-performance epoxy resin composite materias are widely used in the manufacturing of aircraft fuselage, wings and other components; In the field of electronic appliances, epoxy resin adhesives are used for packaging and fixing electronic components.

4,4'-Methylenedianiline field | Shaanxi BLOOM Tech Co., Ltd
4,4'-Methylenedianiline polyimide | Shaanxi BLOOM Tech Co., Ltd

Important sources of heat-resistant polymers and polyisocyanate monomers

It also plays a crucial role in the production of heat-resistant polymers and polyisocyanate monomers. It is mainly used for synthesizing high-performance materials such as polyimide and polyurethane elastomers.

1. Polyimide synthesis
Polyimide is a polymer materia with excellent heat resistance, insulation, and mechanical properties. High performance polyimide resins and films can be synthesized using it.

These materias have broad application prospects in aerospace, electronics and electrical fields, and can meet the needs of extreme conditions such as high temperature and high pressure.

2. Polyurethane elastomer chain extender
In the manufacturing of polyurethane elastomers, as an important component of chain extenders, it can increase the length and crosslinking density of polyurethane molecular chains. This makes polyurethane elastomers have superior elasticity, wear resistance, and chemical corrosion resistance.

 

4,4'-Methylenedianiline chain | Shaanxi BLOOM Tech Co., Ltd
4,4'-Methylenedianiline application | Shaanxi BLOOM Tech Co., Ltd

They have broad application prospects in fields such as automobile manufacturing, shoe materias, and seals.

3. Synthesis of polyisocyanate monomers
4,4'-Methylenedianiline can also be used to synthesize chemicals such as polyisocyanate monomers. These polyisocyanate monomers are important raw materias for manufacturing polyurethane foam, coatings and other high-performance materias. They have broad application prospects in fields such as construction, furniture, and automobiles, providing a rich selection of materias for these industries.

Frequently Asked Questions
 
 

What is 4 4 methylenedianiline pubchem?

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4,4'-Methylenedianiline is an industrial chemical that is not known to occur naturally. It is also commonly known as diaminodiphenylmethane or MDA. It occurs as a colorless to pale yellow solid and has a faint odor.

What is the solubility of 4 4 methylenedianiline?

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MDA has a log Kow of 1.59, a water solubility of 1.25 g/l and a vapour pressure of 2.87X10- 8hPa. MDA is not expected to be volatile and to undergo hydrolysis.

What is 4 4 methylenedianiline used for?

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It occurs as a colorless to pale yellow solid and has a faint odor. 4,4'-Methylenedianiline is used mainly for making polyurethane foams, which have a variety of uses, such as insulating materials in mailing containers. It is also used for making coating materials, glues, Spandex® fiber, dyes, and rubber.

What is the formula for 4 4 methylenedianiline?

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4,4′-Methylenedianiline (MDA) is an organic compound with the formula CH 2(C 6H 4NH 2) 2. It is a colorless solid, although commercial samples can appear yellow or brown.

What is Tetraglycidyl 4 4 methylenedianiline?

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Tetraglycidyl-4,4'-methylenedianiline (TGMDA) is an aniline epoxy resin used in, for example, resin systems of pre-impregnated composite materials (prepregs) of the aircraft industry.

 

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