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ZRO2 Powder is the main oxide of zirconium. Usually, it is a white odorless and tasteless crystal, which is difficult to dissolve in water, hydrochloric acid and dilute sulfuric acid. It usually contains a small amount of hafnium dioxide. It has inactive chemical properties, high melting point, high resistivity, high refractive index and low thermal expansion coefficient, which makes it an important high-temperature resistant material, ceramic insulating material and ceramic shading agent. It is also the main raw material of artificial drilling. The band gap is about 5-7ev. It is monoclinic at low temperature, forming tetragonal crystal above 1100 ℃ and cubic crystal above 1900 ℃. zirconium oxide zro2, molecular formula O2Zr, CAS 1314-23-4, is a metal oxide with high melting point, high hardness, and high chemical stability.
The crystal structure with a cubic crystal system belongs to the P63mc space group. At high temperatures, the crystal structure of zro2 undergoes a transformation from a cubic structure to a monoclinic structure. Usually white or light yellow, high-purity zirconia is colorless and transparent. Has high refractive index and low dispersion. Lower coefficient of thermal expansion, approximately 7.5 × 10 ^ -6 K ^ -1. This low coefficient of thermal expansion gives zirconia an advantage in manufacturing high-temperature sensors and optical devices. Its refractive index is about 2.15, and its dispersion coefficient is about 0.06. This high refractive index and low dispersion make zirconium dioxide zro2 widely used in optical devices and coatings. It has extensive application value in the ceramic and glass industries. By adding an appropriate amount of zirconia, the performance and quality of ceramics and glass products can be improved, and their aesthetics and reliability can be improved. With the continuous development of technology, the application fields of zirconia in the ceramic and glass industries will continue to expand, bringing more convenience and benefits to human production and life.

|
Chemical Formula |
O2Zr |
|
Exact Mass |
122 |
|
Molecular Weight |
123 |
|
m/z |
122 (100.0%), 126 (33.8%), 124 (33.3%), 123 (21.8%), 128 (5.4%) |
|
Elemental Analysis |
O, 25.97; Zr, 74.03 |
|
Morphological |
powder |
|
Color |
white |
|
Melting point |
2700 ° C (lit.) |
|
Boiling point |
5000 ° C (lit.) |
|
Density |
5.89 g / ml at 25 ° C (lit.) |
|
Flash point |
5000 ° C |
|
|
|

ZRO2 Powder has a series of unique physical properties, such as high melting point, high hardness, high chemical stability, low thermal expansion coefficient, and good optical properties, which make it widely used in many fields. The following are the main uses of zirconia:
1. Ceramic and glass industry:
With high melting point and chemical stability, it is used as an additive in the ceramic and glass industry. Adding zirconia can improve the properties of ceramic products, such as increasing strength, wear resistance, and high temperature resistance. In addition, zirconia can also serve as a clarifying agent in the glass industry, improving the transparency and quality of glass products.
1.1. Ceramic Industry:
(1) Toughening and reinforcing agents: can be used as toughening and reinforcing agents for ceramic materials. In ceramic products, it is possible to refine the grain size of ceramic materials, improve their toughness, strength, and impact resistance. By adding an appropriate amount of zirconia, the wear resistance, fatigue resistance, and high-temperature resistance of ceramic materials can be improved.
(2) Coating and Glazing: Can be used for coating and glazing ceramic products. Coatings have high hardness, wear resistance, and corrosion resistance, which can protect the surface of ceramic products from damage. At the same time, glazing can also improve the aesthetics and glossiness of ceramic products, making them more attractive.
(3) Porcelain whitening agent: It has a high whiteness and can be used as a porcelain whitening agent. Adding an appropriate amount of this product to porcelain products can significantly improve their whiteness and transparency, making them more aesthetically pleasing.
(4) Structural ceramics: can be used to manufacture structural ceramics. Structural ceramics are ceramic materials with high strength, high hardness, high temperature resistance, and corrosion resistance, widely used in fields such as machinery, electronics, aerospace, and so on. In structural ceramics, its high hardness, high wear resistance, and high temperature resistance can be utilized to improve the service life and reliability of structural ceramics.
1.2. Glass Industry:
(1) Glass clarifier: It can be used as a glass clarifier to improve the transparency and quality of glass products. In the glass manufacturing process, adding an appropriate amount of zirconia can promote the melting and clarification of glass, reduce the generation of bubbles and microcracks, and improve the toughness and impact resistance of glass products.
(2) Special glass: It can be used to manufacture special glass, such as high-strength glass, high-temperature resistant glass, and optical glass. Among these special glasses, their high hardness, high wear resistance, and high temperature resistance can be utilized to improve their performance and reliability.
(3) Glass fiber: can be used to manufacture glass fiber. Glass fiber is a fiber material with lightweight, high strength, corrosion resistance, and insulation properties, widely used in fields such as architecture, automobiles, aerospace, etc. In glass fiber, its strength and toughness can be improved, and its processing and usage performance can be improved.
2. Electronics industry:
With high hardness and low thermal conductivity, it is used as a raw material for ceramic capacitors, piezoelectric crystals, and semiconductor devices in the electronics industry. It can also be used to manufacture high-temperature sensors and actuators.

2.1. Electronic Ceramics:
It can be used to manufacture electronic ceramics. Electronic ceramics are a ceramic material with excellent electrical, thermal, and mechanical properties, widely used in fields such as electronics, communication, aerospace, etc. In electronic ceramics, its high hardness, high wear resistance, and chemical stability can be utilized to improve the wear resistance, corrosion resistance, and impact resistance of electronic ceramics. In addition, it can also be used as a dielectric material for electronic ceramics, manufacturing electronic components such as capacitors and piezoelectric crystals.
2.2. Integrated Circuit Packaging:
It can be used to manufacture integrated circuit packaging. Integrated circuit packaging is a structure that encapsulates integrated circuit chips in a protective shell, which can protect chips from environmental influences and mechanical damage. In integrated circuit packaging, its high melting point, high chemical stability, and excellent insulation performance can be utilized to improve the reliability and stability of integrated circuit packaging.

2.3. High temperature sensor:
It can be used to manufacture high-temperature sensors. High temperature sensors are sensors that can measure high temperatures and are widely used in industrial production, aerospace, and other fields. In high-temperature sensors, their high melting point, high chemical stability, and excellent thermal conductivity can be utilized to improve the measurement accuracy and service life of high-temperature sensors.
2.4. Laser:
It can be used to manufacture lasers. A laser is a device that can emit lasers and is widely used in fields such as medicine, communication, and industry. In lasers, its high refractive index, low dispersion, and excellent chemical stability can be utilized to improve the output power and beam quality of the laser.

2.5. Solid electrolyte for fuel cells:
It can be used to manufacture solid electrolytes for fuel cells. Fuel cells are devices that convert chemical energy into electrical energy, with solid electrolytes being an important component. In solid electrolytes of fuel cells, their high ionic conductivity and chemical stability can be utilized to improve the energy density and service life of fuel cells.
3. Optical industry:
With high refractive index and low dispersion, it is used as a raw material for high refractive index lenses and contact lenses in the optical industry. It can also be used for manufacturing lasers and high-strength laser lenses.
3.1. High refractive index lenses:
Due to its high refractive index and low dispersion, it is widely used in the optical industry to manufacture high refractive index lenses. High refractive index lenses can reduce the reflection loss of incident light, improve the transmittance and imaging quality of optical systems. In optical instruments such as photography, cameras, and telescopes, high refractive index lenses can improve the clarity and brightness of imaging.

3.2. Contact lenses:
It is also used in the manufacturing of contact lenses. Contact lenses need to have high oxygen permeability and good comfort, and their high refractive index and low dispersion characteristics can meet these requirements. By using zirconia, thinner and softer contact lenses can be manufactured, improving wear comfort and oxygen permeability.
3.3. Laser and High Intensity Laser Lens:
It can be used for manufacturing lasers and high-strength laser lenses. Laser requires the use of high reflectivity and wear resistant lens materials with high hardness, high wear resistance, and chemical stability, which can meet these requirements. In high intensity laser systems, zirconia lenses can withstand high-energy laser beam irradiation, protecting other optical components from damage.
3.4. Fiber optic communication:
It is also applied in fiber optic communication. Fiber optic communication is a communication method that utilizes light waves to transmit information in optical fibers, with advantages such as long transmission distance, fast transmission speed, and large transmission capacity. It can be used to manufacture optical components such as fiber optic connectors and fiber optic jackets, improving the transmission quality and stability of fiber optic communication systems.
3.5. Solar cells:
It can be used to manufacture solar cells. Solar cells require the use of optical thin films to increase the absorption efficiency of light, with high refractive index and low dispersion characteristics, which can optimize the optical performance of solar cells. By using zirconia thin film, the photoelectric conversion efficiency and power generation of solar cells can be improved.

4. Raw materials of metal zirconium and its compounds:
Used for making metal zirconium and zirconium compounds, fire-resistant bricks and crucibles, high-frequency ceramics, abrasive materials, ceramic pigments and zirconate, mainly used for piezoelectric ceramic products, daily ceramics, refractory materials and zirconium bricks, zirconium tubes and crucibles for smelting precious metals. It is also used in the production of steel and non-ferrous metals, optical glass and zirconia fibers. It is also used for ceramic pigments, electrostatic coatings and baking paints. Used in epoxy resin to increase the corrosion of heat-resistant brine.
5. Refractory:
Zirconia fiber is a kind of polycrystalline refractory fiber material. Due to the high melting point, non oxidation and other high temperature excellent characteristics of ZrO2 material itself, ZRO2 Powder fiber has higher service temperature than alumina fiber, mullite fiber, aluminum silicate fiber and other refractory fiber varieties.

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The detailed steps for synthesizing zirconia by laboratory precipitation method are as follows:
Preparation of raw materials: Prepare the required zirconium salts and alkalis, such as zirconium nitrate and sodium hydroxide. These raw materials should be analytically pure to ensure that the synthesized zirconia has a high purity.
Preparation of zirconate precipitation: Mix zirconate and alkali in a certain stoichiometric ratio, and stir evenly. At this point, zirconium ions react with hydroxide ions to form zirconate precipitates. The chemical equation for this process is:
ZrCl4(aq) + 4NaOH(aq) → Zr(OH)4(s)+ 4NaCl (aq).
Filtering and washing: Use a vacuum pump and filter paper or centrifuge to filter out the precipitate, and wash repeatedly with deionized water to remove excess impurities. Be careful when washing to avoid sediment loss.
Oxidation treatment: Mix the filtered zirconate precipitate with an appropriate amount of oxidant (such as nitric acid, hydrogen peroxide, etc.), control the reaction temperature and time, and oxidize the zirconate to produce zirconia and water. The chemical equation for this process is:
Zr(OH)4(s) + 2HNO3(aq) → ZrO2(s) + 2H2O(l) + 2NO3-(aq).
Drying: After washing the product thoroughly, place it in an oven or dryer for drying to remove any moisture. When drying, temperature and time should be controlled to avoid decomposition or deformation of zirconia.
Grinding and screening: The dried zirconia can be ground and screened to ensure that its particle size and morphology meet the requirements of experiments or industrial applications.
Frequently Asked Questions
What is Boron Oxide and how is it produced?
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Boron Oxide, also known as Boron Trioxide, is an inorganic compound with the chemical formula B₂O₃. It is typically produced by burning boron at high temperatures (above 700 °C) or by dehydrating orthoboric acid (H₃BO₃). The compound appears as a white, glassy solid or powder and is known for its high melting point (around 450 °C) and excellent thermal stability.
What are the main applications of Boron Oxide?
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Boron Oxide has a wide range of applications across various industries. It is extensively used in the glass and ceramic industries to improve heat resistance, mechanical strength, and chemical stability. It also serves as a flux in metallurgy, a catalyst in organic synthesis, and a precursor for the production of high-performance boron compounds like boron nitride. Additionally, it finds use in flame retardants, optical glasses, and as a neutron absorber in nuclear applications.
Is Boron Oxide hazardous to health?
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While Boron Oxide is not highly toxic, prolonged or excessive exposure can have negative health effects. Inhaling Boron Oxide dust may cause respiratory irritation, coughing, and asthma-like symptoms. Direct contact with the skin or eyes can also cause irritation. Therefore, it is essential to handle Boron Oxide with care, using appropriate personal protective equipment (PPE) such as masks, gloves, and eye protection.
How does Boron Oxide contribute to glass manufacturing?
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In glass manufacturing, Boron Oxide plays a crucial role in lowering the melting point of glass mixtures, which reduces energy consumption during production. It also improves the thermal shock resistance of glass, making it more durable and suitable for applications that involve rapid temperature changes, such as laboratory glassware and cookware. Furthermore, Boron Oxide enhances the chemical stability of glass, making it more resistant to corrosion by acids and other chemicals.
Can Boron Oxide be used as a catalyst in chemical reactions?
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Yes, Boron Oxide exhibits excellent catalytic properties and is widely used as a catalyst in various organic synthesis reactions. It can accelerate processes such as alcohol etherification, esterification, and cross-condensation reactions, improving reaction rates and yields. Its Lewis acid characteristics make it particularly effective in facilitating reactions that involve the transfer of electron pairs, thereby playing a vital role in the synthesis of complex organic compounds.
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